White Hall is a city in Washington Township, Jefferson County, Arkansas, with a population of 5,526 in the 2010 census. It is included in the Pine Bluff Metropolitan Statistical Area and the greater Little Rock-North Little Rock-Pine Bluff Combined Statistical Area. The city is home to the Pine Bluff Arsenal.DemographicsAs of the census of 2000, there were 4,732 people, 1,780 households, and 1,418 families residing in the city. The population density was 692.1 people per square mile (267.1/km²). There were 1,925 housing units at an average density of 281.6 per square mile (108.7/km²). The racial makeup of the city was 92.54% White, 4.65% Black or African American, 0.49% Native American, 1.31% Asian, 0.34% from other races, and 0.68% from two or more races. 1.04% of the population were Hispanic or Latino of any race.There were 1,780 households out of which 39.9% had children under the age of 18 living with them, 66.5% were married couples living together, 9.7% had a female householder with no husband present, and 20.3% were non-families. 18.0% of all households were made up of individuals and 6.6% had someone living alone who was 65 years of age or older. The average household size was 2.66 and the average family size was 3.02.